ZIF-8材料的制备及应用进展

沸石咪唑酯骨架材料(Zeolitic Imidazolate Framework-8,ZIF-8)是由Zn（Ⅱ）与2-甲基咪唑配位自组装形成的多孔结晶材料,具有可调的孔径、高稳定的结构和催化活性等特点,近年来ZIF-8的制备和应用展现出巨大的潜力并引起了广泛关注。本文总结了目前ZIF-8的制备方法,在此基础上介绍了ZIF-8的形成机理及粒径调控方法,重点综述了ZIF-8及其复合材料在吸附分离、催化、生物医学等领域应用的研究进展,并展望了其应用前景与发展方向,以期为ZIF-8 的应用发展开拓新的思路。     

Mathematical analysis of autonomous and non-autonomous age-structured reaction-diffusion-advection population model

In this paper, we study an age-structured reaction-diffusion-advection population model. First, we use a non-densely defined operator to the linear age-structured reaction-diffusion-advection population model in a patchy environment. By spectral analysis, we obtain the asynchronous exponential growth of the population model. Then we consider nonlinear death rate and birth rate, which all depend on the function related to the generalized total population, and we prove the existence of a steady state of the system. Finally, we study the age-structured reaction-diffusion-advection population model in non-autonomous situations. We give the comparison principle and prove the eventual compactness of semiflow by using integrated semigroup. We also prove the existence of compact attractors under the periodic situation.     

Synthesis and Chromatographic Evaluation of Perfluorooctyl Stationary Phase for Separation of Basic Compounds

Fluorinated stationary phases provide unique separation effect on basic compounds, due to the fluorine atoms, and pentafluorophenyl stationary phases (PFPs) are the most widely used. Considering that some fluoroalkyls have higher fluorine contents than PFPs do, it is speculated that fluoroalkyl stationary phases should have potential new applications. Herein, we synthesized a silica-based stationary phase bonding perfluoroctyl (FC8) proved by characterization through elemental analysis and solid-state ¹³C cross-polarization/magic-anglespinning nuclear magnetic resonance. The chromatographic behavior of the stationary phase was evaluated with test compounds. In addition, to further study the applicability of FC8 materials, Corydalis decumbens (Thunb.) Pers. fraction, considered as a challenging medicine on reversed-phase chromatography columns, was chosen as a test sample. Results demonstrated that the FC8 stationary phase had better and more satisfactory separation performance than the PFP stationary phase on basic compounds.

     

参数激励与强迫激励联合作用下非线性振动系统的余维2退化分叉

在本文里我们首先研究了具有Z_2-对称性的范式理论和退化向量场的普适开折理论。然后利用上述理论研究了参数激励与强迫激励联合作用下非线性振动系统的余维2退化分叉,从而解决了当解具有两个零特征值时解的稳定性问题。最后利用Melnikov方法求出了参数平面上的同宿分叉曲线,讨论了全局分叉的存在性。     

1／2亚谐共振──主参数共振情况下非线性振动系统的余维2退化分叉

本文应用Normal Form理论和退化向量场的普适开折理论研究了参数激励与强迫激励联合作用下非线性振动系统的余维2退化分叉,用Melnikov方法讨论了全局分叉的存在性.     

给定寿命下的焊趾疲劳裂纹深度尺寸分析

本文提供并用统计方法研究了焊趾疲劳裂纹扩展的Ｎ～α曲线族，给出了联系给定裂纹尺寸下的疲劳分布，给定疲劳寿命下的裂纹尺寸分布以及随机初始条件的概率相容条件。研究表明，给定寿命下的焊趾疲劳裂纹深度尺寸α服从分布Ф［（μ（ａ）－ｌｏｇＮ）／σ（ａ）］。     

求解完全强非线性自治系统周期解及其稳定性的三变量迭代法

本文提出用广义位移x,基波幅值变化率da/dt=A(a)和系统频率ω(a)进行迭代的一种解析方法——三变量迭代法,求解一般的二阶完全强非线性自治系统的周期解及其稳定性。通过若干实例计算,表明了该方法行之有效。     

建筑物内火灾烟羽流和顶蓬射流诱发的空气运动盐水模拟实验研究

盐水在清水中的扩散与火灾烟气在空气中的蔓延相似，因而可用盐水的扩散来模拟火灾烟气的蔓延；同样地，由于盐水的扩散而导致的环境清水的运动也可用来模拟烟气蔓延诱发的空气运动。基于这一原理，本文用实验的方法，研究了建筑物内初起火灾产生的烟羽流和顶蓬射流所诱发的空气运动，并对走廊空气层生长规律和运动特性进行了初步的测量和分析。所得结果基本合理，对建筑物通风排烟及疏散通道设计有帮助，从而为建筑火灾环境空气的运动的实验研究开辟了新的思路，也为火灾区域模拟提供了实验依据     

Nonequilibrium thermodynamics of pseudoelasticity

Solid-solid phase transitions often exhibit hystereses, and a hysteresis indicates energy dissipation. Pseudoelasticity refers to a hysteretic loadingunloading characteristic observed in the stress-induced martensitic transformation of shape memory alloys.This paper describes the thermodynamic model ofideal pseudoelasticity, a largely schematized adaptation of the experimental observations, and it reviews the works of other authors on thermodynamics of pseudoelasticity. Different approaches vary widely and we have chosen to put them into perspective by contrasting their assumptions and predictions against those of ideal pseudoelasticity.Ideal pseudoelasticity receives support from the experimental results of Fu [1] and its thermodynamic properties have been exploited by Huo [2]. The model makes use of an analytical ansatz proposed by Müller [3] in which the hysteresis is assumed to be due to the presence of a coherency energy in solid phase mixtures. This model permits the study of stability of the equilibrium states and the calculation of the energy dissipation or entropy production during the phase transition: The equilibrium states of a phase mixture are found to be unstable in load-controlled processes and the dissipated energy is related to the coherency coefficient.We also discuss some open problems concerning the states inside the hysteresis loop and the formation of interfaces.     

SDS-Based Biomembrane Mimetic Chromatography for Prediction of Human Drug Transport as an in Vitro Technique

The main oral drug absorption barriers are fluid cell membranes, and generally drugs are absorbed by a passive diffusion mechanism. On the other hand, the blood–brain barrier (BBB) is considered to be the main barrier to drug transport into the central nervous system (CNS). The BBB restricts the passive diffusion of many drugs from blood to brain. Biopartitioning micellar chromatography (BMC), a mode of micellar liquid chromatography that uses micellar mobile phases in adequate experimental conditions, can be useful as an in vitro system in mimicking the drug partitioning process into biological systems. In this study, relationships between the BMC retention data of a heterogeneous set of 12 drugs and their pharmacokinetics parameters (human oral drug absorption and BBB penetration ability) are studied and the predictive ability of the models is evaluated. Modeling of log k _BMC of these compounds was established by multiple linear regression in two different concentrations (0.07 and 0.09 M) of sodium dodecyl sulfate (SDS). The results showed a fair correlation between human oral drug absorption and BMC retention data in 0.09 M SDS (R ² = 0.864) and a good correlation between the blood–brain distribution coefficient and BMC retention data in 0.07 M of SDS (R ² = 0.887). Application of the developed models to a prediction set demonstrated that the model is also reliable with good predictive accuracy. The external and internal validation results showed that the predicted values are in good agreement with the experimental value.